Preheat oven to 350 degrees Fahrenheit. Grease and line 3 8-inch cake pans with parchment paper. Set aside.
Sift the dry ingredients (flour, sugar, cocoa powder, baking powder, baking soda, and salt) into a large bowl.
Pour in the hot water, sour cream, oil, vanilla, and eggs into a separate bowl and whisk together until fully incorporated.
Mix the wet ingredients into the dry ingredients just until they're incorporated into the batter. The batter will be on the thin side, but that’s the consistency you're after.
Divide the batter evenly between the prepared cake pans, and bake for 23-26 minutes or until a toothpick comes out with a few moist crumbs.
Remove the cake layers from the oven and let them cool in the pans for about 10 minutes. Gently run an offset spatula around the rim of the cake pans to loosen them, then flip them into wire racks to finish cooling.
Once cooled, use a serrated knife to level the top of each cake layer.