Place the finely chopped chocolate (white, milk, semi-sweet or dark) or candy melts in a large heatproof bowl.
Heat for 30 seconds at a medium high-heat (I do a power level 7 out of 10). If you don't have a microwave you can also use a double boiler.
Remove from the microwave and stir the chocolate. It won't be melted much yet, but this helps make sure the chocolate is evenly heated and that certain areas don't overheat/overcook.
Heat for an additional 15 seconds on medium-high power and stir again. If you're using chocolate, check the temperature of the chocolate with your food thermometer between intervals and make sure it doesn't go above 90 F / 32 C.
Repeat until the chocolate is mostly (but not fully melted). Let it sit for a minute, then give the chocolate one more stir to make sure it's nice and smooth.
Use a clean / food-safe paint brush to brush an even layer of melted chocolate or melted candy melts all around the mold.
Immediately insert a popsicle stick in and out of the mold to keep the opening free of chocolate.
Chill the mold in the fridge (or freezer if you're using candy melts) for about 3 minutes or until the chocolate is firm to the touch.
Paint on a second layer of melted chocolate, being sure to add a little extra chocolate around the edge of each cavity. Insert and remove a popsicle stick again.
Refrigerate for another 3 minutes (or freeze if you're using candy melts) until the chocolate is firm to the touch.