Preheat the oven to 350°F / 175°C. Line and grease 3 eight-inch cake pans, or 4 seven-inch pans.
Combine 2 cups all-purpose flour, 2 cups sugar, 3/4 cup black cocoa, 2 tsp baking powder, 1 1/2 tsp baking soda, and 1 tsp salt in a large bowl. Whisk together until combined.
Add 1 cup of hot water and 2 tsp of instant espresso or coffee in a separate, medium-sized bowl. Stir until dissolved. Then add 1 cup buttermilk, 1/2 cup oil, 2 eggs, and 2 tsp vanilla extract to the instant espresso mixture. Give the mixture a quick whisk to combine the ingredients.
Pour the wet ingredients into the dry ingredients. Whisk together until the ingredients are fully incorporated. Note: The batter will be thin!
Divide the batter evenly between the cake pans (490g per pan if you're making 3 layers) and bake for about 24-27 minutes, or until a toothpick inserted into the center comes out with a few moist crumbs.
Remove the cake layers from the oven and let them cool in the pans for about 10 minutes. Gently run an offset spatula around the rim of the cake pans to loosen them, then flip them onto wire racks to finish cooling.
Once cooled, use a serrated knife to level the top of each cake layer. If you make these in advance, wrap and freeze them at this point.